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101.
Melinda Fekete Pál Kolonits Ngo Thi Hien Lajos Novák 《Central European Journal of Chemistry》2005,3(4):792-802
New tryptamine 5, 7 and β-carboline derivatives 3 were preparated by palladium-catalyzed coupling reaction of 5-bromotryptamine 1 with aryl boronic acids.
Dedicated to Professor András Lipták on his 70th birthday. 相似文献
102.
Masanari KimuraRyutaro Mukai Naoko TanigawaShuji Tanaka Yoshinao Tamaru 《Tetrahedron》2003,59(39):7767-7777
Without prior activation of allyl alcohols, allylation of a variety of active methylene compounds with allyl alcohols proceeds smoothly at rt-50°C in the presence of catalytic amounts of Pd(OAc)2 (1-10 mol%), Et3B (30-240 mol%), a phosphine ligand (1-20 mol%), and a base (0 to 50-60 mol%). 相似文献
103.
配合物[Pd(phen)Cl2]与腺嘌呤的键合作用研究 总被引:1,自引:0,他引:1
合成并表征了固体三元配合物[Pd(phen)Cl2] 1. 以1和DNA的组成小分子腺嘌呤(ade)反应, 获得双核配合物单晶[Pd2(phen)2(ade)2]Cl2•4.5H2O (2). 配合物2为正交晶系, 空间群为Pnma, 晶胞参数a=2.1709(9) nm, b=1.4378(6) nm, c=1.2274(5) nm, α=β=γ=90°, V=3.8311(3) nm3, Dc=1.729 g/cm3, Z=4, F(000)=2004, R1=0.0766, wR2=0.1526. phen配体以两个氮原子与钯(II)离子配位, 按生物学原子规范标号, ade以N(3), N(9)原子与钯(II)离子桥联配位, 形成双核混配型配合物. 相似文献
104.
贵金属对钴基催化剂上肉桂醛选择加氢反应的影响 总被引:5,自引:0,他引:5
研究了贵金属改性的Co/γ-Al2O3催化剂上的肉桂醛选择加氢反应.结果表明,通过Pt,Pd和Ru贵金属改性,提高了催化剂的活性,但只有Pt改性的催化剂具有较高的选择性.w(Pt)<0.5%时,催化剂的活性随着Pt含量的增加呈直线升高,当w(Pt)=0.5%时,催化剂活性可提高近5倍,但催化剂的选择性变化很小.XRD结果表明,催化剂经还原后,γ-Al2O3上的钴主要为α-Co0.TPR结果表明,Pt的加入提高了Co3O4的还原性能,且Pt含量越高,Co3O4的还原温度越低.XPS结果表明,Pt改性的催化剂样品,其Co3O4大部分被还原为Co0.由于Pt与Co具有协同效应,故Pt改性的Co/γ-Al2O3催化剂既具有较高的活性,又具有很高的选择性. 相似文献
105.
CO2氧化异丁烷制异丁烯用Pd/V2O5-SiO2催化剂 总被引:4,自引:0,他引:4
利用表面化学反应改性法制备了不同V2O5负载量的V2O5-SiO2表面复合物载体,进而采用等体积浸渍法制备了负载型Pd催化剂. 用N2吸附、 X射线衍射、透射电镜、 X射线光电子能谱、程序升温脱附、化学吸附-红外光谱和微反技术对系列Pd/V2O5-SiO2催化剂的比表面积、晶相结构、价态、异丁烷的化学吸附性能和CO2部分氧化异丁烷制异丁烯的催化性能进行了研究. 结果表明, Pd/V2O5-SiO2催化剂中的钒以V5+形式存在, V5+在催化剂表面形成活性位V=O, 其中 V=O 晶格氧与 i-C4H10分子的-CH3 和-CH 中的H产生化学吸附作用; 催化剂中金属Pd与V4+协同作用使CO2在催化剂上产生了卧式吸附态; 晶格氧参加了催化氧化反应,催化剂中 V5+←→V4+ 的变化构成了催化反应的氧化还原过程. 在525 ℃, CO2/i-C4H10体积比为1和空速为 1200 h-1的条件下,以Pd/25%V2O5-SiO2为催化剂时异丁烷转化率为22.8%, 异丁烯选择性为89.1%. 相似文献
106.
Alexander I. Titkov Alexey N. Salanov Segrey V. Koscheev Andrey I. Boronin 《Reaction Kinetics and Catalysis Letters》2005,86(2):371-379
Summary The interaction of O2with Pd(110) has been studied by TDS and XPS at T = 400 K and at pressures PO2 from 2.6x10-6to 10 Pa. At low exposures in O2(e£1-5 L), an adsorption layer withqof ca.0.5 and with the O1s peak at BE = 529.3 eV has been found to form on the surface. Whenegrows from 5 to 108L, the position and intensity of the oxygen O1s peak remain practically constant. At the same time, as much as 5 mL of oxygen
is absorbed according to the TDS data. The results obtained by TDS and XPS indicate that oxygen penetrates deep into the subsurface
layers of palladium (315-20 ?) and is distributed in its bulk in a low concentration. 相似文献
107.
108.
Flögel O Dash J Brüdgam I Hartl H Reissig HU 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(17):4283-4290
Addition of lithiated methoxyallene to pivalonitrile afforded after aqueous workup the expected iminoallene 1 in excellent yield. Treatment of this intermediate with silver nitrate accomplished the desired cyclization to the electron-rich pyrrole derivative 2 in moderate yield. Surprisingly, trifluoroacetic acid converted iminoallene 1 to a mixture of enamide 3 and trifluoromethyl-substituted pyridinol 4 (together with its tautomer 5). A plausible mechanism proposed for this intriguing transformation involves addition of trifluoroacetate to the central allene carbon atom of an allenyl iminium intermediate as crucial step. Enamide 3 is converted to pyridinol 4 by an intramolecular aldol-type process. A practical direct synthesis of trifluoromethyl-substituted pyridinols 4, 10, 11, and 12 starting from typical nitriles and methoxyallene was established. Pyridinol 10 shows an interesting crystal packing with three molecules in the elementary cell and a remarkable helical supramolecular arrangement. Trifluoromethyl-substituted pyridinol 4 was converted to the corresponding pyridyl nonaflate 13, which is an excellent precursor for palladium-catalyzed reactions leading to pyridine derivatives 14-16 in good to excellent yields. The new synthesis of trifluoromethyl-substituted pyridines disclosed here demonstrates a novel reactivity pattern of lithiated methoxyallene which is incorporated into the products as the unusual tripolar synthon B. 相似文献
109.
Céline Jousse-KarinthiFatima Zouhiri Jacqueline MahuteauDidier Desmaële 《Tetrahedron》2003,59(12):2093-2099
The palladium-catalyzed condensation of a variety of active methylene compounds with methyl 6-acetoxymethyl-hepta-2,6-dienoate was investigated. The six-membered adducts resulting from a η3 palladium complex alkylation-Michael addition sequence were obtained with moderate to good yields. In some cases, further evolution of the primary adduct was observed. The process has been expanded to access nitrogen heterocycles by using sodium p-toluenesulfonamide as the nucleophilic partner. 相似文献
110.
Rui Qi SONG * Jian Qing ZENG Bing ZHONG Guangzhou Institute of Chemistry Chinese Academy of Sciences Guangzhou State Key Laboratory of Coal Chemistry Institute of Coal Chemistry Chinese Academy of Sciences Taiyuan School of 《中国化学快报》2002,13(10)
We have studied the palladium-catalyzed alkoxycarbonylation of allyl bromide in supercritical (sc) CO2 and found the reaction rate in sc CO2 was lower than those in some organic solvents1. The possible reason was the lower solubility of sc CO2 for the palladium catalyst. As an effective approach to improve the solubility of varieties of solutes, cosolvent such as ethanol has been widely used in the sc CO2 extraction2,3. Based on the above consideration, we chose several organic reagents… 相似文献